1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane → Carbon Dioxide

HRID 866364노트

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HRID 866364 반응식
[C:1]([I:20])([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[C:21](=O)([O-:25])[O:22]CC.C(C(OCC)=O)(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F.C(C(O)=O)(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F>[Cu].[Zn].CS(C)=O>[C:1]([I:20])([C:4]([C:7]([C:10]([C:13]([C:16]([F:17])([F:18])[F:19])([F:14])[F:15])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[C:21](=[O:25])=[O:22]

참가 물질

8

반응물 4

HCID 677331,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexaneHCID 67818Perfluoroheptanoic acidHCID 526468Ethyl perfluoroheptanoateHCID 21226545CID 21226545

생성물 2

HCID 280Carbon DioxideHCID 677331,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane

시약·촉매·용매 2

HCID 10290809Zinc copper couple촉매HCID 679Dimethyl Sulfoxide용매2회

실험 절차

44.6 g. of C6F13I and 12 g. of ethyl carbonate are dissolved in 30 ml. of DMSO and added slowly to a dispersion of 18 g. of zinc-copper couple in 40 ml. of DMSO. At the end of the addition, which lasts 3 hours, the reaction mixture is centrifuged and by decanting a yellow liquid is obtained and identified by comparison of NMR and infrared spectra with that of a sample of C6F13COOC2H5 prepared by esterification of the acid, C6F13COOH, obtained by reaction of C6F13I and of CO2.

후처리

  1. additionAt the end of the addition, which
  2. customby decanting a yellow liquid
  3. customis obtained

출처 및 근거

ORD 기록
ord-2ac0cf53b9194d39a65f0d00b7ba8cc5
출처 데이터셋
uspto-grants-1978_07
특허 번호
US04098806

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