Benzoyl Peroxide → Methacrylic Acid

HRID 866824Notes

Reaction equation

HRID 866824 reaction equation
[C:1]1([CH3:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:8](OCCOCC)(=O)C.[C:17]([O:25][O:26][C:27](=[O:34])[C:28]1[CH:33]=CC=C[CH:29]=1)(=[O:24])[C:18]1[CH:23]=CC=C[CH:19]=1>>[C:17]([O:25][CH2:5][CH2:6][CH2:1][CH3:7])(=[O:24])[CH:18]=[CH2:19].[C:27]([O:26][CH3:8])(=[O:34])[C:28]([CH3:29])=[CH2:33].[CH2:8]=[CH:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:17]([OH:25])(=[O:24])[C:18]([CH3:23])=[CH2:19]

Participants

6

Reactant 2

HCID 7187Benzoyl PeroxideHCID 70401118HCID 70401118, compound

Product 4

HCID 4093Methacrylic AcidHCID 6658Methyl MethacrylateHCID 7501StyreneHCID 8846Butyl Acrylate

Procedure

Butyl acrylate (288.0 g.) methyl methacrylate (60.0 g.), styrene (96.0 g.), methacrylic acid (36.0 g.) are polymerized in 75/25//toluene/2-ethoxyethyl acetate as described in Example 1 using benzoyl peroxide initiator. The final copolymer has a viscosity of 275 cps. at 25° C. and 40.4% solids.

Workup

  1. customat 25° C.

Sources & evidence

ORD record
ord-0b0b90797afe488cbfe9b88a9224f36d
Source dataset
uspto-grants-1978_07
Patent number
US04101606

Reaction notes

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