HCID 519133, compound → HCID 70618756, compound

HRID 866849Notes

Reaction equation

HRID 866849 reaction equation
[CH2:1]([P:4](Cl)Cl)[CH2:2][CH3:3].[Cl:7][C:8]1[CH:13]=[CH:12][C:11]([Mg]Br)=[CH:10][CH:9]=1>C(Cl)(Cl)Cl>[Cl:7][C:8]1[CH:13]=[CH:12][C:11]([CH:3]([C:11]2[CH:12]=[CH:13][C:8]([Cl:7])=[CH:9][CH:10]=2)[CH2:2][CH2:1][PH2:4])=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 519133HCID 519133, compoundHCID 178478191HCID 178478191, compound

Product 1

HCID 70618756HCID 70618756, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Bis(p-chlorophenyl)propylphosphine was prepared by reacting 0.2 mole of propyldichlorophosphine with 0.4 mole of p-chlorophenylmagnesium bromide. The product was isolated by chloroform extraction and distillation as previously described. The portion boiling between 160° and 165° C. under a pressure of 2 mm. Hg was collected. The analysis corresponded to bis(p-chlorophenyl)propylphosphine.

Workup

  1. customboiling between 160° and 165° C. under a pressure of 2 mm. Hg
  2. customwas collected

Sources & evidence

ORD record
ord-3f9073a68f8240ffbf241315bc49eaa1
Source dataset
uspto-grants-1978_07
Patent number
US04101655

Reaction notes

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