Bromine → 2-Amino-3-bromo-N,N-diethyl-5-methoxy-benzylamine

HRID 866959Notes

Reaction equation

HRID 866959 reaction equation
[NH2:1][C:2]1[CH:13]=[CH:12][C:11]([O:14][CH3:15])=[CH:10][C:3]=1[CH2:4][N:5]([CH2:8][CH3:9])[CH2:6][CH3:7].[Br:16]Br>C(Cl)Cl>[NH2:1][C:2]1[C:13]([Br:16])=[CH:12][C:11]([O:14][CH3:15])=[CH:10][C:3]=1[CH2:4][N:5]([CH2:8][CH3:9])[CH2:6][CH3:7]

Participants

4

Reactant 2

HCID 24408BromineHCID 4220092-Amino-N,N-diethyl-5-methoxy-benzylamine

Product 1

HCID 203192402-Amino-3-bromo-N,N-diethyl-5-methoxy-benzylamine

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2-Amino-3-bromo-N,N-diethyl-5-methoxy-benzylamine was prepared from 2-amino-N,N-diethyl-5-methoxy-benzylamine and bromine analogous to Example 9. Proof of structure by IR-, UV- and NMR-spectra. IR-spectrum (methylenechloride): 3250 cm-1NH2 ; 3410 cm-1NH2 ; 2830 cm-1OCH3 ; 2800 cm-1N-ethyl; 1480 cm-1C=C; 1590 cm-1C=C.

Sources & evidence

ORD record
ord-dfa5916725ad4205abe48c5ad5157beb
Source dataset
uspto-grants-1978_07
Patent number
US04101671

Reaction notes

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