HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dicyandiamide → 6-[2-Chloro-5-(trifluoromethyl)phenyl]-1,3,5-triazine-2,4-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dicyandiamide | HCID 10005 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 2-Chloro-5-(trifluoromethyl)benzonitrile | HCID 67604 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Diglyme | HCID 8150 | — |
| Product | 6-[2-Chloro-5-(trifluoromethyl)phenyl]-1,3,5-triazine-2,4-diamine | HCID 23275234 | — |
Reaction Steps
4.0 g of 3-cyano-4-chlorobenzotrifluoride (90°-102° C./29 mm Hg), 2.0 g of dicyanodiamide and 1.0 g of caustic potash are refluxed in 10 ml of diglyme for 3 hours. After cooling, the mixture is diluted with water and the separated crystals are recrystallized from methanol. Melting point: 210°-212° C.; yield: 3.8 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04103009 |
| Source dataset | uspto-grants-1978_07 |
| ORD ID | ord-a4201581b50c48388fce64fa2b23b05b |
| Source note | uspto-grants-1978_07 |