Lithium Benzoate → HCID 12647149, compound

HRID 868189Notes

Reaction equation

HRID 868189 reaction equation
Cl[CH2:2][C:3]([O-:5])=[O:4].[Li+].[C:7]([O-:15])(=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[Li+]>CN(C=O)C>[C:7]([O:15][CH2:2][C:3]([OH:5])=[O:4])(=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 2724073Lithium BenzoateHCID 23695591Lithium chloroacetate

Product 1

HCID 12647149HCID 12647149, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

13 g lithium chloroacetate (0.10 m) and 17.6 g lithium benzoate (0.10 m) were combined in a 250 ml R.b. flask with 50 ml DMF. This was heated on an oil bath to 110°-120° C. with magnetic stirring for 3 hrs. (The solution at first was clear, but after 2-3 hrs. a white precipitate formed).

Workup

  1. temperatureThis was heated on an oil bath to 110°-120° C.
  2. wait(The solution at first was clear, but after 2-3 hrs
  3. customa white precipitate formed)

Sources & evidence

ORD record
ord-f5a88c206f824151aa5d91d1cf601598
Source dataset
uspto-grants-1988_10
Patent number
US04778618

Reaction notes

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