2-Chloroethyl methyl sulfide → (n-Hexylthio) Ethyl Isothiocyanate

HRID 868694Notes

Reaction equation

HRID 868694 reaction equation
[CH2:1]([S:7][CH2:8][CH2:9]Cl)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].CSCCCl.C(SCC[S:25][C:26]#[N:27])CCCCC>>[CH2:1]([S:7][CH2:8][CH2:9][N:27]=[C:26]=[S:25])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

4

Reactant 3

HCID 109652-Chloroethyl methyl sulfideHCID 122602791-((2-Chloroethyl)thio)hexaneHCID 131715735n-C6H13SCH2CH2SCN

Product 1

HCID 53861891(n-Hexylthio) Ethyl Isothiocyanate

Procedure

Example 1 is repeated with the exception that n-C6H13SCH2CH2Cl is used as a reagent instead of CH3SCH2CH2Cl and the reaction is allowed to proceed for seventy-five minutes. The product is isolated by distillation at reduced pressure and analyzed by gas chromatography/mass spectrometry which shows that the product is 0.7 percent n-C6H13SCH2CH2SCN and 97.0 percent n-C6H13SCH2CH2NCS.

Workup

  1. waitto proceed for seventy-five minutes
  2. customThe product is isolated by distillation at reduced pressure

Sources & evidence

ORD record
ord-8ef64004375d4d72b748aa63791b4535
Source dataset
uspto-grants-1988_10
Patent number
US04780557

Reaction notes

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