Acetic Acid → HCID 178420909, compound

HRID 872370Notes

Reaction equation

HRID 872370 reaction equation
C(O)(=O)C.OO.[NH:7]1[CH:11]=[N:10][C:9]([SH:12])=[N:8]1.[OH-].[Na+]>O>[NH:7]1[CH:11]=[N:10][C:9]([S:12][S:12][C:9]2[N:10]=[CH:11][NH:7][N:8]=2)=[N:8]1

Participants

6

Reactant 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 14798Sodium HydroxideHCID 178527894HCID 178527894, compound

Product 1

HCID 178420909HCID 178420909, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Glacial acetic acid (7.89 g) was added to 18.7 g of a 15% aqueous hydrogen peroxide solution. The resulting solution was added slowly to a solution prepared from 16.5 g 1,2,4-triazole-3-thiol, 160 g of water and 16.3 g 40% NaOH. The reaction temperature was moderated with the use of an ice bath during the addition. After stirring overnight at room temperature, the product was filtered, washed with water and then dried under vacuum at 70 C.

Workup

  1. additionThe resulting solution was added slowly to a solution
  2. additionThe reaction temperature was moderated with the use of an ice bath during the addition
  3. filtrationthe product was filtered
  4. washwashed with water
  5. customdried under vacuum at 70 C

Sources & evidence

ORD record
ord-41002310b54642d0bec66ed35ab85ce1
Source dataset
uspto-grants-2015_03
Patent number
US08975316B2

Reaction notes

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