HRID882

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10539870

未命名化合物

$结构：C/C(C=O)=C\[C@H]1CC[C@H](O[Si](C)(C)C(C)(C)C)CC1$

HCID178418459

未命名化合物

HCID178418471

未命名化合物

PRODUCTS

生成物

$结构：C/C(=C\[C@H]1CC[C@H](O[Si](C)(C)C(C)(C)C)CC1)C(O)CCCc1ccccc1$

HCID178418375

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

The alcohol 137 was prepared from the crude aldehyde 136. and 1.5 mL (0.75 mmol) of 120 in 2.0 mL of THF as described above for the synthesis of alcohol 121 in Example 1 to give 220 mg of the crude diastereomeric alcohol 137. Flash chromatography (elution with 20% ethyl acetate in hexane) afforded 146 mg of the alcohol 137 as an oil. 1H NMR consistent with structure.