Ammonium Chloride → HCID 66808566, compound

HRID 883985Notes

Reaction equation

HRID 883985 reaction equation
[F:1][C:2]1[CH:26]=[CH:25][C:24]([F:27])=[CH:23][C:3]=1[CH2:4][O:5][C:6]1[CH:11]=[CH:10][C:9]([S:12][C:13]2[CH:18]=[CH:17][C:16]([OH:19])=[CH:15][CH:14]=2)=[C:8]([N+:20]([O-])=O)[CH:7]=1.[NH4+].[Cl-]>[Fe]>[NH2:20][C:8]1[CH:7]=[C:6]([O:5][CH2:4][C:3]2[CH:23]=[C:24]([F:27])[CH:25]=[CH:26][C:2]=2[F:1])[CH:11]=[CH:10][C:9]=1[S:12][C:13]1[CH:18]=[CH:17][C:16]([OH:19])=[CH:15][CH:14]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 66808519HCID 66808519, compound

Product 1

HCID 66808566HCID 66808566, compoundYield 86.1%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 86c (1.70 g, 4.2 mmol) was reacted with Fe and NH4Cl as described in Example 10E to give the title compound (1.3 g, 84%).

Sources & evidence

ORD record
ord-2b2728aff9574cf7bff3114aac4e78fa
Source dataset
uspto-grants-2012_08
Patent number
US08236950B2

Reaction notes

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