Atrolactic acid → HCID 86649661, compound

HRID 884334Notes

Reaction equation

[NH2:1][C@H:2]([C:13]([OH:15])=[O:14])[CH2:3][C:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[NH:6][CH:5]=1.[C:16]1([C:22]([CH3:27])([OH:26])[C:23]([OH:25])=[O:24])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.N[C@@H](C(O)=O)CC1C2C(=CC=CC=2)NC=1.N[C@H](C(O)=O)CC1C=CC=CC=1>>[C:16]1([C:22]([CH3:27])([OH:26])[C:23]([OH:25])=[O:24])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[NH2:1][C@H:2]([C:13]([OH:15])=[O:14])[CH2:3][C:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[NH:6][CH:5]=1

Participants

Reactant 4

HCID 1303Atrolactic acid

HCID 6140L-Phenylalanine

HCID 6305L-Tryptophan3×

HCID 9060D-Tryptophan

Product 1

HCID 86649661HCID 86649661, compound

Procedure

To compare effects of combinations of tryptophan enantiomers and phenyllactic acid enantiomers, aqueous solutions of 400 ppm of L-tryptophan, D-tryptophan (Wako Pure Chemical Industries, Ltd.), L-phenyllactic acid (Sigma-Aldrich Japan), and D-phenyllactic acid (Sigma-Aldrich Japan) were prepared. Separately, aqueous solutions of 200 ppm of each of the tryptophan enantiomers and 200 ppm of each of the phenylalanine enantiomers were prepared and subjected to the adzuki bean root promotion assay in the same way as in Example 1.

Workup

customwere prepared

Sources & evidence

ORD record: ord-1eae6615da644d76b877a737749266a1
Source dataset: uspto-grants-2012_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08242054B2

Reaction notes

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