Ethanol → Methyl 5-aminonaphthalene-1-carboxylate

HRID 88538Notes

Reaction equation

HRID 88538 reaction equation
[C:23](=[O:24])([O-:25])[OH:26].[CH3:28][CH2:29][O:30][C:31](=[O:32])[CH3:33].[CH3:34][CH2:35][OH:36].[N+:6]([O-:7])(=[O:8])[c:9]1[c:10]2[cH:11][cH:12][cH:13][c:14]([C:19](=[O:20])[O:21][CH3:22])[c:15]2[cH:16][cH:17][cH:18]1.[Na+:27].[OH2:1].[OH2:2].[Sn:3]([Cl:4])[Cl:5]>>[NH2:6][c:9]1[c:10]2[cH:11][cH:12][cH:13][c:14]([C:19](=[O:20])[O:21][CH3:22])[c:15]2[cH:16][cH:17][cH:18]1

Participants

8

Reactant 7

HCID 702EthanolHCID 769Bicarbonate IonHCID 923Sodium ionHCID 962Water2×HCID 8857Ethyl AcetateHCID 24479Stannous ChlorideHCID 15893378Methyl 5-nitronaphthalene-1-carboxylate

Product 1

HCID 23423651Methyl 5-aminonaphthalene-1-carboxylate

Sources & evidence

ORD record
ord-b06998c6d8df46e492c76c14cd5d9594
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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