HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuric Acid → 2-Bromo-1-tert-butyl-4-nitrobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 1-tert-Butyl-4-nitrobenzene | HCID 76773 | — |
| Catalyst | HCID 178418844 | HCID 178418844 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2-Bromo-1-tert-butyl-4-nitrobenzene | HCID 238587 | — |
Reaction Steps
Bromine (17.4 ml) was added dropwise over 40 min to a stirred mixture of 4-tert-butylnitrobenzene (59.5 g, 332 mmol), silver(II) sulfate (56.5 g, 181 mmol), H2SO4 (300 ml), and H2O (33 ml) at RT. The mixture was stirred for a further 3 h and then poured into 0.1 M Na2S2O5/H2O (1 L)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08247430B2 |
| Source dataset | uspto-grants-2012_08 |
| ORD ID | ord-04ef3a87ad9a47e799ebc1de91b6cd08 |
| Source note | uspto-grants-2012_08 |