Oxygen → 2-Octanone

HRID 890844Notes

Reaction equation

HRID 890844 reaction equation
[CH3:1][CH:2]([OH:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(OC(C1C=C2C(=O)N(O)C(=O)C2=CC=1)=O)CCCCCCCCCCC.O=O>C([O-])(=O)C.[Co+2].C([O-])(=O)C>[CH3:1][C:2](=[O:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

5

Reactant 3

HCID 977OxygenHCID 200832-OctanolHCID 109157654-dodecyloxycarbonyl-N-hydroxyphthalimide

Product 1

HCID 80932-OctanoneYield 6.3%

Reagents, catalysts & solvents 1

HCID 6277Cobalt diacetateCatalyst

Procedure

A mixture of 24 mmol of 2-octanol, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide and 0.005 mmol of cobalt(II) acetate was stirred at 70° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 3 hours and thereby yielded 1.52 mmol of 2-octanone.

Sources & evidence

ORD record
ord-c1b7a0db0ab240eba3910e0783e86d85
Source dataset
uspto-grants-2006_02
Patent number
US06998491B2

Reaction notes

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