Carbon Tetrachloride → HCID 22244967, compound

HRID 891221Notes

Reaction equation

HRID 891221 reaction equation
ClCl.[NH2:3][C:4]1[N:9]=[C:8](SC)[N:7]=[C:6]([C:12]([Cl:15])([CH3:14])[CH3:13])[N:5]=1.[Cl:16]C(Cl)(Cl)Cl.C(=O)([O-])[O-].[K+].[K+]>ClC(Cl)Cl>[NH2:3][C:4]1[N:9]=[C:8]([Cl:16])[N:7]=[C:6]([C:12]([Cl:15])([CH3:14])[CH3:13])[N:5]=1

Participants

6

Reactant 4

HCID 5943Carbon TetrachlorideHCID 11430Potassium CarbonateHCID 24526ChlorineHCID 22244966HCID 22244966, compound

Product 1

HCID 22244967HCID 22244967, compoundYield 10%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Chlorine gas was passed at 35 to 40° C. into a solution of 5 g of 2-amino-4-methylthio-6-(1-chloroisopropyl)-1,3,5-triazine in 0.1 l of trichloromethane (or tetrachloromethane) (15 min). 10 g of potassium carbonate were added to the reaction mixture at room temperature, and the mixture was stirred for 5 minutes and filtered and the solvent removed in vacuo. This gave a product mixture in which approximately 0.5 g (10%) of 2-amino-4-chloro-6-(1-chloroisopropyl)-1,3,5-triazine are present (detection by HPLC comparison with 100% product).

Workup

  1. filtrationfiltered
  2. customthe solvent removed in vacuo

Sources & evidence

ORD record
ord-a933a009c8454182bbac58b5d811d7f3
Source dataset
uspto-grants-2006_02
Patent number
US07002011B1

Reaction notes

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