HCID 178432216, compound → HCID 178432215, compound

HRID 892344Notes

Reaction equation

HRID 892344 reaction equation
[CH3:1][C:2]1[NH:6][C:5]2[CH:7]=[CH:8][C:9]([CH2:11][OH:12])=[CH:10][C:4]=2[N:3]=1>CN(C=O)C.[O-2].[Mn+4].[O-2]>[CH3:1][C:2]1[NH:6][C:5]2[CH:7]=[CH:8][C:9]([CH:11]=[O:12])=[CH:10][C:4]=2[N:3]=1

Participants

4

Reactant 1

HCID 178432216HCID 178432216, compound

Product 1

HCID 178432215HCID 178432215, compound

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 6228DimethylformamideSolvent

Procedure

24.4 g (0.15 mol) of 18c in 400 ml of DMF are stirred with 84.8 g (0.975 mol) of manganese(IV) oxide at room temperature for 3 days in analogy to Example 8b.

Sources & evidence

ORD record
ord-78226d9de4134a998733841181f66e36
Source dataset
uspto-grants-1992_06
Patent number
USRE033948

Reaction notes

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