HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → ethyl 1-[N-(4-bromophenyl)-N-methylaminocarbonyl]cyclopropanecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzenamine, 4-bromo-N-methyl- | HCID 2757052 | — |
| Reactant | Ethyl 1-chlorocarbonylcyclopropanecarboxylate | HCID 14233946 | — |
| Product | ethyl 1-[N-(4-bromophenyl)-N-methylaminocarbonyl]cyclopropanecarboxylate | HCID 19096870 | 50% |
Reaction Steps
Ethyl 1-chlorocarbonylcyclopropanecarboxylate (3.11 grams, 0.02 mole), prepared in Example XVIII, 4-bromo-N-methylaniline (3.00 grams, 0.02 mole) and triethylamine (1.63 grams, 0.02 mole) were reacted in a manner similar to that described in Example III to give 3.79 grams (0.01 mole) of ethyl 1-[N-(4-bromophenyl)-N-methylaminocarbonyl]cyclopropanecarboxylate isolated as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05123951 |
| Source dataset | uspto-grants-1992_06 |
| ORD ID | ord-026c00b5de054f2980d7e9ed1e0d88d3 |
| Source note | uspto-grants-1992_06 |