HCID 19096800, compound → HCID 19891467, compound

HRID 893238Notes

Reaction equation

HRID 893238 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([NH:9][C:10](=[O:20])[C:11]([CH3:19])([S:17][CH3:18])[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:5]=[C:6]([Cl:8])[CH:7]=1.Cl[O-:22].[Na+]>O.C(Cl)Cl>[Cl:1][C:2]1[CH:3]=[C:4]([NH:9][C:10](=[O:20])[C:11]([CH3:19])([S:17]([CH3:18])=[O:22])[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:5]=[C:6]([Cl:8])[CH:7]=1

Participants

4

Reactant 2

HCID 19096800HCID 19096800, compoundHCID 23665760Sodium Hypochlorite

Product 1

HCID 19891467HCID 19891467, compound

Reagents, catalysts & solvents 1

HCID 21908982Water methylene chlorideSolvent

Procedure

Ethyl 3-[(3,5-dichlorophenyl)amino]-2-methyl-2-methylthio-3-oxopropanoate, prepared in Example XC (Compound 261), was reacted with aqueous sodium hypochlorite in a water-methylene chloride mixture in a manner similar to that described in Example XCIII to give ethyl 3-[(3,5-dichlorophenyl)amino]-2-methyl-2-methylsulfinyl-3-oxopropanoate having a melting point of 124° C.-127° C.

Sources & evidence

ORD record
ord-fb96271bde544ec49afd109da816358e
Source dataset
uspto-grants-1992_06
Patent number
US05123951

Reaction notes

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