m-Chloroperbenzoic acid → HCID 12926047, compound

HRID 894637Notes

Reaction equation

HRID 894637 reaction equation
[CH3:1][S:2][C:3]1[CH:14]=[CH:13][C:6]2[O:7][C:8]3([C:11](=[O:12])[C:5]=2[CH:4]=1)[CH2:10][CH2:9]3.ClC1C=CC=C(C(OO)=[O:23])C=1>>[CH3:1][S:2]([C:3]1[CH:14]=[CH:13][C:6]2[O:7][C:8]3([C:11](=[O:12])[C:5]=2[CH:4]=1)[CH2:10][CH2:9]3)=[O:23]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 12926045HCID 12926045, compound

Product 1

HCID 12926047HCID 12926047, compoundYield 76.3%

Procedure

5-Methylthiospiro[benzo[b]furan-2(3H), 1'-cyclopropane]-3-one (600 mg.) and m-chloroperbenzoic acid (627 mg.) were allowed to react in the same manner as Example 65. The product was recrystallized from ethyl acetate-hexane to give colorless prisms of 5-methylsulfinylspiro[benzo[b]furan-2(3H), 1'-cyclopropane]-3-one (493 mg.). m.p. 87°-90° C.

Workup

  1. customto react in the same manner as Example 65
  2. customThe product was recrystallized from ethyl acetate-hexane

Sources & evidence

ORD record
ord-0388dc331f7a41ac9a0e8f937f6e576a
Source dataset
uspto-grants-1981_08
Patent number
US04284644

Reaction notes

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