Phthaloyl chloride → Stearoyl chloride

HRID 894874Notes

Reaction equation

HRID 894874 reaction equation
C(C1C=C(C)C(CNC)=C(C)C=1O)(C)(C)C.C(C1C=C(C)C(CNCCO)=C(C)C=1O)(C)(C)C.[C:35](Cl)(=O)[C:36]1[C:37](=[CH:41][CH:42]=[CH:43][CH:44]=1)[C:38]([Cl:40])=[O:39].[C:47](Cl)(=O)[CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][C:56](Cl)=O>>[C:38]([Cl:40])(=[O:39])[CH2:37][CH2:41][CH2:42][CH2:43][CH2:44][CH2:36][CH2:35][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH3:56]

Participants

5

Reactant 4

HCID 6955Phthaloyl chlorideHCID 66072Sebacoyl chlorideHCID 205748086-tert.-butyl-3-[N-(2-hydroxyethyl)aminomethyl]-2,4-xylenolHCID 205748106-tert.-butyl-3-(N-methylaminomethyl)-2,4-xylenol

Product 1

HCID 8212Stearoyl chloride

Procedure

By an analogous procedure to that described in the first part of Example 16 and using 6-tert.-butyl-3-(N-methylaminomethyl)-2,4-xylenol (produced as described in the first part of Example 22) in place of 6-tert.-butyl-3-[N-(2-hydroxyethyl)aminomethyl]-2,4-xylenol and phthalic acid dichloride and sebacic acid dichloride, respectively, in place of stearoyl chloride, the following compounds, respectively, are produced: ##STR69##

Workup

  1. customproduced

Sources & evidence

ORD record
ord-92af67ba8e5d4115be73c3c4eec9a319
Source dataset
uspto-grants-1981_08
Patent number
US04284790

Reaction notes

Loading…