HuagongsheHuagongshe Chemistry Print Report · For research reference only
Decalin → HCID 69117901, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Decalin | HCID 7044 | — |
| Reactant | 2-Allyloxy-2',6'-dichloro-5-fluorobiphenyl | HCID 69117526 | — |
| Product | HCID 69117901 | HCID 69117901 | 84% |
Reaction Steps
A solution of 2-allyloxy-2′,6′-dichloro-5-fluorobiphenyl (11.02 g, 37 mmol) in decahydronaphthalene (100 mL) was refluxed for 38 h. The solvent was removed under vacuum. Chromatography with 0–20% ethyl acetate in hexanes afforded 9.26 g (84%) of 3-ally-2′,6′-dichloro-5-fluorobiphenyl-2-ol as a light yellow oil. MS (ES) m/z 295.0 ([M−H]−).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07365095B2 |
| Source dataset | uspto-grants-2008_04 |
| ORD ID | ord-abcd63b1db3e47a1845fd4d75ce3f374 |
| Source note | uspto-grants-2008_04 |