Potassium Bromide → HCID 11952592, compound

HRID 902593Notes

Reaction equation

[OH:1][C:2]1[CH:3]=[C:4]([CH:38]=[CH:39][C:40]=1[N+:41]([O-])=O)[O:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]([C:21]2[CH:26]=[CH:25][C:24]([O:27][C:28]3[CH:33]=[CH:32][C:31]([N+:34]([O-])=O)=[C:30]([OH:37])[CH:29]=3)=[CH:23][CH:22]=2)([C:17]([F:20])([F:19])[F:18])[C:13]([F:16])([F:15])[F:14])=[CH:8][CH:7]=1.[K+].[Br-]>>[NH2:41][C:40]1[CH:39]=[CH:38][C:4]([O:5][C:6]2[CH:11]=[CH:10][C:9]([C:12]([C:21]3[CH:22]=[CH:23][C:24]([O:27][C:28]4[CH:33]=[CH:32][C:31]([NH2:34])=[C:30]([OH:37])[CH:29]=4)=[CH:25][CH:26]=3)([C:17]([F:18])([F:19])[F:20])[C:13]([F:15])([F:16])[F:14])=[CH:8][CH:7]=2)=[CH:3][C:2]=1[OH:1]

Participants

Reactant 2

HCID 253877Potassium Bromide

HCID 11952593HCID 11952593, compound

Product 1

HCID 11952592HCID 11952592, compoundYield 81.7%

Procedure

2,2-Bis(4-(4-amino-3-hydroxyphenoxy)phenyl)hexafluoropropane was synthesized in a manner analogous to Example 2 from 2,2-bis(4-(3-hydroxy-4-nitrophenoxy)phenyl)hexafluoropropane. Yield: 81.7%; mp 178˜181° C.; IR (KBr): 3380, 3250, 1599, 1500 cm−1; MS (EI) m/z 550 (M+, 100); Elemental Anal. Calcd. for C27H20F6N2O4: C, 58.91; H, 3.64; N, 5.09. Found: C, 58.73; H, 3.72; N, 5.00.

Sources & evidence

ORD record: ord-9f7ff247ba104dab88d0dbaa9575d170
Source dataset: uspto-grants-2008_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07365231B2

Reaction notes

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