Hydrochloric Acid → HCID 23336336, compound

HRID 903528Notes

Reaction equation

HRID 903528 reaction equation
[CH2:1]([O:3][P:4]([N:14]([CH:18]([CH3:20])[CH3:19])[CH:15]([CH3:17])[CH3:16])([CH2:6][C:7]([O:9][CH:10]([CH3:13])[CH2:11]C)=[O:8])=[O:5])[CH3:2].[ClH:21].[Cl:22][O-].[Na+]>>[Cl:21][C:6]([Cl:22])([P:4]([O:3][CH2:1][CH3:2])([N:14]([CH:18]([CH3:20])[CH3:19])[CH:15]([CH3:17])[CH3:16])=[O:5])[C:7]([O:9][CH:10]([CH3:13])[CH3:11])=[O:8]

Participants

4

Reactant 3

HCID 313Hydrochloric AcidHCID 23336329HCID 23336329, compoundHCID 23665760Sodium Hypochlorite

Product 1

HCID 23336336HCID 23336336, compound

Procedure

To 100 ml of 5.25 percent sodium hypochlorite solution (Clorox®) was added 6.0 g of 1-methylpropyl 2-[ethoxy di(1-methylethyl)aminophosphinyl]acetate dropwise. The pH was maintained at 10.5-11.0 by simultaneous addition of 1 N HCl solution. The reaction mixture was stirred an additional 45 minutes then extracted with methylene chloride. The methylene chloride solution was dried and stripped in vacuum to give 6.2 g of 1-methylethyl 2,2-dichloro-2-[ethoxy di(1-methylethyl)aminophosphinyl]acetate as an acid.

Workup

  1. extractionthen extracted with methylene chloride
  2. dry with materialThe methylene chloride solution was dried

Sources & evidence

ORD record
ord-6cc65f6930ac4993941a2e916714861f
Source dataset
uspto-grants-1980_10
Patent number
US04228109

Reaction notes

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