HuagongsheHuagongshe Chemistry Print Report · For research reference only
Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- → Tetracyanoquinodimethane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- | HCID 73696 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Tetracyanoquinodimethane | HCID 73697 | — |
Reaction Steps
According to the procedure of Fatiadi Synthesis, 1976, 133, incorporated herein by reference, the 1,4-bis(dicyanomethylene)cyclohexane is allowed to react with manganese dioxide in refluxing (110° C.) toluene for ca. 15 minutes to provide TCNQ in ca. 60% yields.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04229364 |
| Source dataset | uspto-grants-1980_10 |
| ORD ID | ord-366e9c2a0e504e51b09d96e9e5139ab7 |
| Source note | uspto-grants-1980_10 |