Sodium Hydroxide → HCID 54413875, compound

HRID 904500Notes

Reaction equation

HRID 904500 reaction equation
[CH2:1]([NH:16][C:17]1[CH:31]=[CH:30][C:20]([C:21]([NH:23][CH2:24][C:25]([O:27]CC)=[O:26])=[O:22])=[CH:19][CH:18]=1)[CH2:2][CH2:3][CH:4]=[CH:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[OH-].[Na+]>C(O)C>[CH2:1]([NH:16][C:17]1[CH:18]=[CH:19][C:20]([C:21]([NH:23][CH2:24][C:25]([OH:27])=[O:26])=[O:22])=[CH:30][CH:31]=1)[CH2:2][CH2:3][CH:4]=[CH:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 54466580HCID 54466580, compound

Product 1

HCID 54413875HCID 54413875, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 26.4 g. of ethyl N-[4-(4-pentadecenylamino)benzoyl]glycinate, 110 ml. of 1 N sodium hydroxide solution, and 100 ml. of ethanol is stirred at ambient temperature for 2 hours and then partially evaporated. The gaseous solution is washed with diethyl ether, acidified with 6 N hydrochloric acid, and filtered. The white solid is dried in vacuo and recrystallized from acetone.

Workup

  1. additionA mixture of 26.4 g
  2. custompartially evaporated
  3. washThe gaseous solution is washed with diethyl ether
  4. filtrationfiltered
  5. customThe white solid is dried in vacuo
  6. customrecrystallized from acetone

Sources & evidence

ORD record
ord-89dbd2932f154171838e78b9f14b801b
Source dataset
uspto-grants-1980_10
Patent number
US04230878

Reaction notes

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