Acetic Acid → 1-Ethoxyethyl acetate

HRID 904978Notes

Reaction equation

HRID 904978 reaction equation
[C:1]([OH:4])(=[O:3])[CH3:2].C(Cl)(=O)C.[CH:9]([O:11][CH2:12][CH3:13])=[CH2:10]>>[C:1]([O:4][CH:9]([O:11][CH2:12][CH3:13])[CH3:10])(=[O:3])[CH3:2]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 6367Acetyl chlorideHCID 8023Ethyl vinyl ether2×

Product 1

HCID 978951-Ethoxyethyl acetate

Conditions

Temperature
30 °C

Procedure

Into a 500 ml reaction flask, equipped with stirrer, cooling bath, thermometer, addition funnel and nitrogen blanket apparatus, is added 60 ml of acetic acid (1.1 moles) and 0.1 ml of acetyl chloride. Dropwise over a period of one hour, while maintaining the reaction mass at 30° C., is added 100 ml (1.0 moles) of ethyl vinyl ether. At the end of the addition of said ethyl vinyl ether, the reaction mass is stirred for a period of twelve hours, while maintaining the temperature thereof at 30° C.

Workup

  1. customInto a 500 ml reaction flask
  2. customequipped with stirrer
  3. temperaturecooling bath
  4. additionthermometer, addition funnel
  5. temperaturewhile maintaining the temperature
  6. customat 30° C.

Sources & evidence

ORD record
ord-8d63ac77c7864f2199dea0df9f5a1d4b
Source dataset
uspto-grants-1983_12
Patent number
US04421125

Reaction notes

Loading…