Water → HCID 15571367, compound

HRID 905047Notes

Reaction equation

HRID 905047 reaction equation
[CH2:1]1[O:9][C:8]2[CH:7]=[CH:6][C:5]([CH:10]3[CH2:15][C:14](=[O:16])[C:13](=[C:17](N4CCOCC4)[CH:18]=[CH:19][C:20]4[CH:25]=[CH:24][C:23]5[O:26][CH2:27][O:28][C:22]=5[CH:21]=4)[C:12](=[O:35])[CH2:11]3)=[CH:4][C:3]=2[O:2]1.[OH2:36].[H][H]>C(O)(=O)C.[C].[Pd]>[CH2:1]1[O:9][C:8]2[CH:7]=[CH:6][C:5]([CH:10]3[CH2:11][C:12](=[O:35])[CH:13]([C:17](=[O:36])[CH2:18][CH2:19][C:20]4[CH:25]=[CH:24][C:23]5[O:26][CH2:27][O:28][C:22]=5[CH:21]=4)[C:14](=[O:16])[CH2:15]3)=[CH:4][C:3]=2[O:2]1

Participants

6

Reactant 3

HCID 962WaterHCID 54036400HCID 54036400, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 15571367HCID 15571367, compound

Reagents, catalysts & solvents 2

HCID 178418390HCID 178418390, compoundCatalystHCID 176Acetic AcidSolvent

Procedure

Similarly, 1.0 g of the above-mentioned enamine type adduct compound, that is, 5-(3,4-methylenedioxyphenyl)-2-[3-(3,4-methylenedioxyphenyl)-1-morpholinoallylidene]-cyclohexane-1,3-dione, was dissolved in 80 ml of acetic acid, and 0.5 g of a 5% palladium-carbon catalyst and 30 ml of deionized water were added to the solution and catalytic reduction was carried out with hydrogen under atmospheric pressure for 4 hours to obtain 0.38 g (the yield being 44%) of the desired compound.

Workup

  1. customto obtain 0.38 g (the yield

Sources & evidence

ORD record
ord-044f06cbc2b3449aa35c923bae4d8a88
Source dataset
uspto-grants-1983_12
Patent number
US04421763

Reaction notes

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