HuagongsheHuagongshe Chemistry Print Report · For research reference only
Heptane → 5-Bromo-2-(methanesulfinyl)pyrimidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Heptane | HCID 8900 | — |
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 5-Bromo-2-(methylsulfanyl)pyrimidine | HCID 4738564 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 5-Bromo-2-(methanesulfinyl)pyrimidine | HCID 20475701 | 90% |
Reaction Steps
The title compound was prepared by oxidation of 2-methylthio-5-bromopyrimidine by m-chloroperbenzoic acid in chloroform as described in Example 39; yield 90%, m.p. 90° C. (n-heptane). 1H NMR (CDCl3): δ2.91 (Me),. 8.90 (H-4, H-6).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04423047 |
| Source dataset | uspto-grants-1983_12 |
| ORD ID | ord-10c85693b78c43fdb9cd41e7d79a859e |
| Source note | uspto-grants-1983_12 |