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HRID905236

反应详情

EQUATION

反应方程式

HRID 905236 的结构方程式

REACTANTS

反应物

3
结构：CCCCCCC
HCID8900

Heptane

C7H16

结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：CSc1ncc(Br)cn1
HCID4738564

5-Bromo-2-(methylthio)pyrimidine

C5H5BrN2S

PRODUCTS

生成物

1
结构：CS(=O)c1ncc(Br)cn1
HCID20475701

5-Bromo-2-(methanesulfinyl)pyrimidine

C5H5BrN2OS

收率 90%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

The title compound was prepared by oxidation of 2-methylthio-5-bromopyrimidine by m-chloroperbenzoic acid in chloroform as described in Example 39; yield 90%, m.p. 90° C. (n-heptane). 1H NMR (CDCl3): δ2.91 (Me),. 8.90 (H-4, H-6).