huagongshe.com
HRID908356

反应详情

EQUATION

反应方程式

HRID 908356 的结构方程式

REACTANTS

反应物

2
结构：CN(C)C(OC(C)(C)C)N(C)C
HCID79885

tert-Butoxy bis(dimethylamino)methane

C9H22N2O

结构：O=C1CCCc2nonc21
HCID543052

6,7-Dihydro-2,1,3-benzoxadiazol-4(5H)-one

C6H6N2O2

PRODUCTS

生成物

1
结构：CN(C)C=C1CCc2nonc2C1=O
HCID67405521

未命名化合物

收率 57.1%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

A THF solution of 4,5,6,7-tetrahydro-2,1,3-benzoxadiazole-4-one 1 g (0.00725 mol) and Bredereck's reagent 1.89 g (0.0109 mol) was stirred at room temperature for 2 days. The crystalline precipitate was filtered, washed with THF and dried, 0.8 g desired product was obtained, the yield is 57%.

WORKUP

后处理

  1. filtrationThe crystalline precipitate was filtered
  2. washwashed with THF
  3. customdried