Methanol → HCID 178515937, compound

Participants

Reaction Steps

0.4 mmol of [Ir(1-phenylisoquinoline)2Cl]2 of Formula 44 and 0.88 mmol of 3-(2H-benzotriazole-2-yl)-4-hydroxyphenyl methane of Formula 45 and 2.0 mmol of sodium carbonate were added to a 250 ml branched flask and dissolved in 40 ml of trichloromethane and 15 mL of methanol to react in a nitrogen atmosphere at room temperature for 2 to 10 hours. After the reaction was completed, the reaction solution was Celite filtered and precipitated in hexane to obtain triazole phenolate represented by Formula 3. The obtained red solid was refined using silica gel column (methylene chloride:acetone=10:1). The structure of the final product was analyzed using a 1H NMR spectrum:

Provenance & Evidence