Piconol → Bis(4,4'-(phenyl-2-pyridylmethoxyboryl)benzyl) ether

HRID 909822Notes

Reaction equation

HRID 909822 reaction equation
[C:1]1([B:7]([CH:9]([O:16][CH:17]([B:24]([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[OH:25])[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.O[CH2:33][C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][N:35]=1>C(O)C>[C:1]1([B:7]([CH:9]([O:16][CH:17]([B:24]([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)[O:25][CH2:33][C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][N:35]=2)[C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[O:8][CH2:33][C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][N:35]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 11474PiconolHCID 67392963Bis(3,3'-(phenylhydroxyboryl)benzyl) ether

Product 1

HCID 67391678Bis(4,4'-(phenyl-2-pyridylmethoxyboryl)benzyl) ether

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The entitled compound (34 mg) was obtained by allowing 59 mg of bis(4,4′-(phenylhydroxyboryl)benzyl) ether and 59 mg of 2-hydroxymethylpyridine to act in 0.7 mL of ethanol at room temperature.

Sources & evidence

ORD record
ord-9646dd375e4241da92d73c4b3084db6e
Source dataset
uspto-grants-2011_09
Patent number
US08017809B2

Reaction notes

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