HCID 59318557, compound → HCID 131729200, compound

Participants

Reaction Steps

<2> The reaction described in <3> of Synthesis Example 1 was performed under the same conditions, except that the phenoxyacetyloxymethyl difluoromethanesulfonic acid sodium salt (3.66 g) produced in <1> of Synthesis Example 5 above was used instead of the benzoyloxymethyldifluorosulfonic acid sodium salt in the reaction with diphenylmethylphenylsulfonium trifluoromethanesulfonic acid sodium salt, and thus 4.35 g (yield 92.5%) of phenoxyacetic acid 2,2-difluoro-2-sulfoethyl ester diphenylmethylphenylsulfonium salt as shown in the following reaction scheme 11 was obtained. The structure of the product was confirmed by 1H-NMR (see FIG. 10).

Provenance & Evidence