Sodium ion → 6,7,12,13-Tetrahydro-3,9-dimethoxy-6,12-dimethyl-5,7-dioxo-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole

HRID 91543Notes

Reaction equation

HRID 91543 reaction equation
[CH3:103][N:104]([CH3:105])[CH:106]=[O:107].[CH3:1][O:2][c:3]1[cH:4][c:5]2[c:6]([cH:7][cH:8]1)[nH:9][c:10]1[c:11]2[c:12]2[c:13]([c:14]3[c:15]4[cH:16][c:17]([O:24][CH3:25])[cH:18][cH:19][c:20]4[n:21]([CH3:23])[c:22]13)[C:26](=[O:30])[NH:27][C:28]2=[O:29].[CH3:31][O:32][C:33]1=[CH:61][c:60]2[c:37]([nH:38][c:39]3[c:40]4[n:41]([CH3:42])[c:43]5[c:44]([cH:45][c:46]([O:47][CH3:48])[cH:49][cH:50]5)[c:51]4[c:52]4[c:58]([c:59]32)[C:56](=[O:57])[N:54]([CH3:55])[CH2:53]4)[C:35](=[O:36])[CH2:34]1.[CH3:62][O:63][c:64]1[cH:65][cH:66][c:67]2[nH:68][c:69]3[c:70]4[nH:71][c:72]5[c:73]([cH:74][c:75]([O:76][CH3:77])[cH:78][cH:79]5)[c:80]4[c:81]4[c:88]([c:89]3[c:90]2[cH:91]1)[C:86](=[O:87])[N:84]([CH3:85])[C:82]4=[O:83].[CH3:92][I:93].[CH3:94][O:95][S:96]([O:97][CH3:98])(=[O:99])=[O:100].[H-:101].[Na+:102]>>[CH3:1][O:2][c:3]1[cH:4][c:5]2[c:6]([cH:7][cH:8]1)[nH:9][c:10]1[c:11]2[c:12]2[c:13]([c:14]3[c:15]4[cH:16][c:17]([O:24][CH3:25])[cH:18][cH:19][c:20]4[n:21]([CH3:23])[c:22]13)[C:26](=[O:30])[N:27]([CH3:31])[C:28]2=[O:29]

Participants

9

Reactant 8

HCID 923Sodium ionHCID 6228DimethylformamideHCID 6328Methyl iodideHCID 6497Dimethyl SulfateHCID 166653HydrideHCID 212168326,7,12,13-tetrahydro-3,9-dimethoxy-6-methyl-5,7-dioxo-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazoleHCID 212168516,7,12,13-tetrahydro-3,9-dimethoxy-12-methyl-5,7-dioxo-5H-indolo[2,3-a]pyrrolo[3,4-c]carbazoleHCID 867539116,7,12,13-tetrahydro-3,9-dimethoxy-6,12-dimethyl-5,1-dioxo-5H-indolo[2,3-a]pyrrolo[3,4-c]-carbazole

Product 1

HCID 212168616,7,12,13-Tetrahydro-3,9-dimethoxy-6,12-dimethyl-5,7-dioxo-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole

Sources & evidence

ORD record
ord-134075d339ee4df6b415ce343e107924
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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