Vinyl Acetate → 6-(Ethenyloxy)-1-hexanol

HRID 916906ノート

反応式

HRID 916906 の反応式
C(=O)([O-])[O-].[Na+].[Na+].C(O)CCCCCO.C(OC=C)(=O)C.[CH:21]([O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][O:30]C=C)=[CH2:22]>C1(C)C=CC=CC=1>[CH:21]([O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][OH:30])=[CH2:22]

参加物

6

反応物 4

HCID 7904Vinyl AcetateHCID 10340Sodium CarbonateHCID 123741,6-HexanediolHCID 882291,6-Bis(vinyloxy)hexane

生成物 1

HCID 220261996-(Ethenyloxy)-1-hexanol

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
100 °C

実験手順

To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (6.7 mg, 0.01 mmol) and sodium carbonate (64 mg, 0.6 mmol) in toluene (1.0 ml), 1,6-hexanediol (118 mg, 1 mmol) and vinyl acetate (344 mg, 4 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that 1,6-bis(vinyloxy)hexane and 6-vinyloxy-1-hexanol were produced in yields of 87% and 2%, respectively, with a conversion from 1,6-hexanediol of 97%.

後処理

  1. additionwere added

出典と根拠

ORDレコード
ord-c2f2faa35b9343c88e8856c3e6936b58
出典データセット
uspto-grants-2007_09
特許番号
US07271297B2

反応ノート

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