HCID 3881907, compound → (3-Phenoxyphenyl)methyl 2-phenylbutanoate

HRID 917863Notes

Reaction equation

HRID 917863 reaction equation
[Cl-].[O:2]([C:9]1[CH:10]=[C:11]([CH:19]=[CH:20][CH:21]=1)[CH2:12][N+]1C=CC=CC=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:22]([CH:24]([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[C:25]([O-:27])=[O:26])[CH3:23]>CN(C)C=O>[CH2:22]([CH:24]([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[C:25]([O:27][CH2:12][C:11]1[CH:19]=[CH:20][CH:21]=[C:9]([O:2][C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH:10]=1)=[O:26])[CH3:23]

Participants

4

Reactant 2

HCID 3881907HCID 3881907, compoundHCID 215229611-[(3-Phenoxyphenyl)methyl]pyridin-1-ium chloride

Product 1

HCID 12895069(3-Phenoxyphenyl)methyl 2-phenylbutanoateYield 156.5%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

4.5 g of 3-phenoxybenzyl pyridinium chloride, 1.4 g of α-ethylphenyl-acetate and 50 ml of dimethylformamide were treated in the same manner as described in Example 1 to obtain 4.65 g of 3-phenoxybenzyl α-ethylphenyl-acetate (nD25 1.5715).

Sources & evidence

ORD record
ord-de6ef1f65c644252a3a254eb43f79d5e
Source dataset
uspto-grants-1976_07
Patent number
US03968124

Reaction notes

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