Tert-Butylbenzene → HCID 13570281, compound

HRID 917929Notes

Reaction equation

[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:11](Cl)(=[O:15])[CH:12]([CH3:14])[CH3:13]>>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([C:11](=[O:15])[CH:12]([CH3:14])[CH3:13])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

Reactant 2

HCID 7366Tert-Butylbenzene

HCID 62325Isobutyryl chloride

Product 1

HCID 13570281HCID 13570281, compound

Procedure

The procedure of Example 3 was followed for the reaction of 67g (0.5 mole) of tert-butylbenzene with 53.3g (0.5 mole) of isobutyryl chloride. Obtained after high vacuum concentration was 88g of a clear liquid; ir (film) 3.4 (m), 5.95 (s), 8.2 (s), 10.2 (s) microns; nmr (CDCl3) 7.65 (4H, d of d) 3.50 (1H, quintet), 1.28 (9H, s) 1.15(6H, d) ppm. A VPC analysis indicated one pure product.

Workup

customObtained
concentrationafter high vacuum concentration

Sources & evidence

ORD record: ord-4fe599c546774c45819a8d2cffec5067
Source dataset: uspto-grants-1976_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03968168

Reaction notes

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