HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tert-Butylbenzene → 1-(4-tert-Butylphenyl)-2-chloropropan-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tert-Butylbenzene | HCID 7366 | — |
| Reactant | 2-Chloropropionyl chloride | HCID 111019 | — |
| Product | 1-(4-tert-Butylphenyl)-2-chloropropan-1-one | HCID 3818617 | — |
Reaction Steps
The procedure of Example 3 was followed for the reaction of 63.5g (0.5 mole) of 2-chloropropionyl chloride with 67g (0.5 mole) of tert-butylbenzene. Obtained after high vacuum concentration was 100g of clear, yellow liquid product: ir (film) 3.4 (s), 5.9 (s), 6.3 (s), 8.0 (s), 10.5 (s), 11.8 (s) microns; nmr (CDCl3) 7.67 (4H, d of d), 5.21 (1H, q), 1.67 (3H, d), 1.28 (9H, s) ppm. A VPC analysis indicated one pure product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03968168 |
| Source dataset | uspto-grants-1976_07 |
| ORD ID | ord-db2e1a64123c4073a4d8e2d7f4a02d06 |
| Source note | uspto-grants-1976_07 |