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HRID918080

反应详情

EQUATION

反应方程式

HRID 918080 的结构方程式

REACTANTS

反应物

2
结构：N
HCID222

Ammonia gas

H3N

结构：O=C1c2ccc([N+](=O)[O-])cc2C(=O)c2c1cccc2[N+](=O)[O-]
HCID74147

1,7-Dinitroanthraquinone

C14H6N2O6

PRODUCTS

生成物

1
结构：Nc1cccc2c1C(=O)c1cc([N+](=O)[O-])ccc1C2=O
HCID20317508

1-Amino-7-nitroanthracene-9,10-dione

C14H8N2O4

收率 97%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCC#N
溶剂HCID7854

Propionitrile

C3H5N

PROCEDURE

实验过程

A mixture of 298 g of 1,7-dinitro-anthraquinone (99%) and 3 liters of propionitrile is reacted with 510 g of ammonia (molar ratio 30 : 1, pressure 60 atmospheres) in an autoclave at 140°C for 4 hours. 260 g of a 97% 1-amino-7-nitro-anthraquinone (95% of the theoretical yield) are obtained after working-up as described in Example 12.