Sodium Iodide → HCID 14662926, compound

HRID 918299Notes

Reaction equation

HRID 918299 reaction equation
[CH3:1][O:2][CH:3]([O:10][CH3:11])[C:4](=[O:9])/[CH:5]=[CH:6]\[CH2:7][CH3:8].[I-].[Na+]>C(O)(=O)C>[CH3:11][O:10][CH:3]([O:2][CH3:1])[C:4](=[O:9])/[CH:5]=[CH:6]/[CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 57417966HCID 57417966, compound2×

Product 1

HCID 14662926HCID 14662926, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The crude product produced in Example V is dissolved in 6 ml of acetic acid with 0.1 g of sodium iodide. By GLC on Carbowax(polyethylene glycol) it is clear that the 1,1-dimethoxy-cis-3-hexene-2-one is converted to a new material of later retention time. After one-half hour less than 5 percent of "cis" material remains.

Workup

  1. waitAfter one-half hour less than 5 percent of "cis" material remains

Sources & evidence

ORD record
ord-40888d0d89e841e3809c8a7502e883ed
Source dataset
uspto-grants-1976_07
Patent number
US03970701

Reaction notes

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