Potassium hydride → HCID 74089332, compound

HRID 918324Notes

Reaction equation

HRID 918324 reaction equation
[CH3:1][O:2][C:3]([CH3:19])([CH3:18])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:17])[CH2:8]/[CH:9]=[CH:10]/[C:11]([CH3:16])=[CH:12][C:13]([OH:15])=[O:14].[H-].[K+:21]>C1C=CC=CC=1>[CH3:1][O:2][C:3]([CH3:18])([CH3:19])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:17])[CH2:8][CH:9]=[CH:10][C:11]([CH3:16])=[CH:12][C:13]([O-:15])=[O:14].[K+:21]

Participants

4

Reactant 2

HCID 82127Potassium hydrideHCID 86733733HCID 86733733, compound

Product 1

HCID 74089332HCID 74089332, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To a solution of 0.5 g. of trans, trans 11-methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid in 15 ml. of benzene is added, with stirring, an equivalent amount of potassium hydride. The mixture is stirred at room temperature for about 2 hours and then evaporated to give potassium 11-methoxy-3,7,11-trimethyldodeca-2,4-dienoate.

Workup

  1. stirringThe mixture is stirred at room temperature for about 2 hours
  2. customevaporated

Sources & evidence

ORD record
ord-43bc25c4ff524d7481d90b6f718772c6
Source dataset
uspto-grants-1976_07
Patent number
US03970704

Reaction notes

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