HRID918408

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：C=C(C)CO[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@H]3[C@@H](O)C[C@]2(C)[C@@]1(O)C(=O)CCl

HCID22791781

未命名化合物

PRODUCTS

生成物

结构：CC1(CO[C@@H]2C[C@H]3[C@@H]4CCC5=CC(=O)C=C[C@]5(C)[C@H]4[C@@H](O)C[C@]3(C)[C@@]2(O)C(=O)CCl)CO1

HCID86733754

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

A solution of 21-chloro-11β,17-dihydroxy-16α-(2-methyl-2-propenyloxy)pregna-1.4-diene-3,20-dione (16 mmoles) in 300 ml of dichloromethane is stirred with 3.2 g of m-chloroperbenzoic acid for 3 hours. The solution is washed with a mixture of 5% sodium bicarbonate solution and 5% sodium sulfite solution, dried, and evaporated to give the title compound.

WORKUP

后处理

washThe solution is washed with a mixture of 5% sodium bicarbonate solution and 5% sodium sulfite solution
customdried
customevaporated