HuagongsheHuagongshe Chemistry Print Report · For research reference only
Metaperiodic acid → HCID 86733755, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Metaperiodic acid | HCID 65185 | — |
| Reactant | HCID 86733754 | HCID 86733754 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 86733755 | HCID 86733755 | — |
Reaction Steps
A solution of 21-chloro-11β,17-dihydroxy-16α-[(2-methyloxiranyl)methoxy]pregna-1,4-diene-3,20-dione (12 mmoles) in 200 ml of tetrahydrofuran is stirred with a solution of 10 g of periodic acid in 20 ml of water for 3 hours. The slurry is diluted with water and extracted with chloroform. The chloroform solution is dried and evaporated in vacuo to give the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03971773 |
| Source dataset | uspto-grants-1976_07 |
| ORD ID | ord-7afbd1b0097c4833841afb56839146d2 |
| Source note | uspto-grants-1976_07 |