反应详情

185 g (2.0 mol) of epichlorhydrin, 30 g of water, 5 g of methanol, and 1.5 g of 32% aqueous solution of sodium hydroxide were put. While these substances were stirred, 35 g (1.0 mol) of hydrogen sulfide was blown to the substances with the liquid temperature being kept at 5 to 15° C. As a result, 210 g (0.96 mol) of bis(3-chloro-2-hydroxypropyl)sulfide was obtained.

1. custombeing kept at 5 to 15° C