Decalin → Decalin

HRID 921595Notes

Reaction equation

HRID 921595 reaction equation
[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[C:7]([O:11][CH2:12][CH2:13][CH2:14][CH3:15])(=[O:10])[CH:8]=[CH2:9].[C:16](#[N:19])[CH:17]=[CH2:18].[CH2:20]1[CH:29]2[CH:24]([CH2:25][CH2:26][CH2:27][CH2:28]2)[CH2:23][CH2:22][CH2:21]1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH2:28]1[CH:29]2[CH:24]([CH2:23][CH2:22][CH2:21][CH2:20]2)[CH2:25][CH2:26][CH2:27]1.[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[C:7]([O:11][CH2:12][CH2:13][CH2:14][CH3:15])(=[O:10])[CH:8]=[CH2:9].[C:16](#[N:19])[CH:17]=[CH2:18]

Participants

7

Reactant 5

HCID 7044DecalinHCID 7187Benzoyl PeroxideHCID 7294Methyl AcrylateHCID 7855AcrylonitrileHCID 8846Butyl Acrylate

Product 2

HCID 7044DecalinHCID 86717696HCID 86717696, compound

Procedure

To a 50 kgf/cm2 pressure resistant autoclave equipped with a stirrer, methyl acrylate 100 parts, n-butyl acrylate 100 parts, acrylonitrile 30 parts, decalin 400 parts and a polymerization initiator constituted by benzoyl peroxide 0.1 part were charged. The mixture was held at 80° C. for 5 hours for solution polymerization to obtain a decalin solution of the methyl acrylate-n-butyl acrylate-acrylonitrile copolymer I. Note that, the obtained methyl acrylate-n-butyl acrylate-acrylonitrile copolymer I dissolved in the decalin and did not have a particulate shape. Next, decalin was added to the obtained solution to adjust it to a solid content concentration 5% and a molecular sieve was used for dehydration.

Workup

  1. customTo a 50 kgf/cm2 pressure resistant autoclave equipped with a stirrer
  2. additionwere charged
  3. customThe mixture was held at 80° C. for 5 hours for solution polymerization

Sources & evidence

ORD record
ord-a9ea916ec4c64d0c86555253d23205a4
Source dataset
uspto-grants-2016_03
Patent number
US09276263B2

Reaction notes

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