Salicylic Acid → HCID 178449049, compound

HRID 921987Notes

Reaction equation

HRID 921987 reaction equation
[C:1]([OH:10])(=[O:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[OH-].[CH2:12]([N+:16]([CH2:22][CH2:23][CH2:24][CH3:25])([CH2:18][CH2:19][CH2:20][CH3:21])[CH3:17])[CH2:13][CH2:14][CH3:15]>CC(C)=O>[C:1]([O-:10])(=[O:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[CH3:17][N+:16]([CH2:12][CH2:13][CH2:14][CH3:15])([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:18][CH2:19][CH2:20][CH3:21].[C:1]([OH:10])(=[O:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4]

Participants

4

Reactant 2

HCID 338Salicylic AcidHCID 36208Ammonium, methyltributyl-, hydroxide

Product 1

HCID 178449049HCID 178449049, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Salicylic acid (5-20 mmol) and tributylmethylammonium hydroxide (5 mmol, 40% solution in H2O) were dissolved in 20 ml of acetone stirred for 15 min at room temperature. The solvent was evaporated and the remaining viscous liquid was dried at 0.1 mbar with stirring for 24 hrs.

Workup

  1. customThe solvent was evaporated
  2. customthe remaining viscous liquid was dried at 0.1 mbar
  3. stirringwith stirring for 24 hrs

Sources & evidence

ORD record
ord-29c8165eeed44795b1359c4b932a1bbe
Source dataset
uspto-grants-2016_03
Patent number
US09278134B2

Reaction notes

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