Ammonium Chloride → HCID 69043906, compound

HRID 925064Notes

Reaction equation

HRID 925064 reaction equation
[F:1][C:2]1[CH:18]=[CH:17][C:5]([CH:6]=[C:7]2[C:15]3[CH2:14][CH2:13][CH2:12][CH2:11][C:10]=3[C:9](=[O:16])[O:8]2)=[CH:4][C:3]=1[N+:19]([O-])=O.[Cl-].[NH4+]>C(O)C.O.[Fe]>[NH2:19][C:3]1[CH:4]=[C:5]([CH:17]=[CH:18][C:2]=1[F:1])[CH:6]=[C:7]1[C:15]2[CH2:14][CH2:13][CH2:12][CH2:11][C:10]=2[C:9](=[O:16])[O:8]1

Participants

6

Reactant 2

HCID 25517Ammonium ChlorideHCID 69044850HCID 69044850, compound

Product 1

HCID 69043906HCID 69043906, compound

Reagents, catalysts & solvents 3

HCID 23925IronCatalystHCID 702EthanolSolventHCID 962WaterSolvent

Procedure

A solution of EXAMPLE 2A (2.25 g) and ammonium chloride (0.83 g) in ethanol (35 mL) and water (25 mL) at 70° C. was treated with iron powder (4.35 g), stirred for 3 hours and filtered through diatomaceous earth (CELITE®, World Minerals, Santa Barbara, Calif.) with hot ethanol. The filtrate was concentrated, and the concentrate was stirred with water for 30 minutes and filtered. The solid was washed with water and dried.

Workup

  1. filtrationfiltered through diatomaceous earth (CELITE®, World Minerals, Santa Barbara, Calif.) with hot ethanol
  2. concentrationThe filtrate was concentrated
  3. stirringthe concentrate was stirred with water for 30 minutes
  4. filtrationfiltered
  5. washThe solid was washed with water
  6. customdried

Sources & evidence

ORD record
ord-5d8672e2d9ef42dfb313c8c7e12df70e
Source dataset
uspto-grants-2016_03
Patent number
US09283222B2

Reaction notes

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