HRID927116

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12213474

未命名化合物

2 次

结构：C=C(c1ccccc1)c1cc(OCc2ccccc2)c(OCc2ccccc2)nn1

HCID86677027

未命名化合物

2 次

结构：C=C(B1OC(C)(C)C(C)(C)O1)c1ccc(C(F)(F)F)cc1

HCID86677032

未命名化合物

2 次

PRODUCTS

生成物

结构：C=C(c1ccc(C(F)(F)F)cc1)c1cc(OCc2ccccc2)c(OCc2ccccc2)nn1

HCID86677034

未命名化合物

收率 48%

PROCEDURE

实验过程

Prepared according to the method for 3,4-bis(benzyloxy)-6-(1-phenylethenyl)pyridazine (Intermediate 25) from 3,4-bis(benzyloxy)-6-chloropyridazine (Intermediate 1) and 4,4,5,5-tetramethyl-2-{1-[4-(trifluoromethyl)-phenyl]ethenyl}-1,3,2-dioxaborolane (Intermediate 66) in 48% yield.

WORKUP

后处理

customPrepared

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c8827ba687c04b40bc388f70523bc1cc
来源数据集: uspto-grants-2016_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09290456B2
来源说明: uspto-grants-2016_03

反应 SMILES

[CH2:1]([O:8][C:9]1[N:10]=[N:11][C:12]([C:23]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)=[CH2:24])=[CH:13][C:14]=1[O:15][CH2:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(OC1N=NC(Cl)=CC=1OCC1C=CC=CC=1)C1C=CC=CC=1.CC1(C)C(C)(C)OB(C(C2C=CC([C:70]([F:73])([F:72])[F:71])=CC=2)=C)O1>>[CH2:1]([O:8][C:9]1[N:10]=[N:11][C:12]([C:23]([C:25]2[CH:30]=[CH:29][C:28]([C:70]([F:73])([F:72])[F:71])=[CH:27][CH:26]=2)=[CH2:24])=[CH:13][C:14]=1[O:15][CH2:16][C:17]1[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1