Solketal → HCID 68209381, compound

HRID 927319Notes

Reaction equation

HRID 927319 reaction equation
[CH3:1][C:2]1([CH3:9])[O:6][CH:5]([CH2:7][OH:8])[CH2:4][O:3]1.[Br:10][C:11]1[CH:23]=[CH:22][C:21]2[C:20]3[C:15](=[CH:16][C:17]([Br:24])=[CH:18][CH:19]=3)[C:14]([CH2:29][CH2:30][CH2:31]Br)([CH2:25][CH2:26][CH2:27]Br)[C:13]=2[CH:12]=1>COCCOC>[Br:10][C:11]1[CH:23]=[CH:22][C:21]2[C:20]3[C:15](=[CH:16][C:17]([Br:24])=[CH:18][CH:19]=3)[C:14]([CH2:25][CH2:26][CH2:27][O:8][CH2:7][CH:5]3[CH2:4][O:3][C:2]([CH3:9])([CH3:1])[O:6]3)([CH2:29][CH2:30][CH2:31][O:8][CH2:7][CH:5]3[CH2:4][O:3][C:2]([CH3:9])([CH3:1])[O:6]3)[C:13]=2[CH:12]=1

Participants

4

Reactant 2

HCID 7528SolketalHCID 67465880HCID 67465880, compound

Product 1

HCID 68209381HCID 68209381, compound

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent2×

Procedure

Potassium terbutylate (3.0 g, 26.7 mmoles) are added, in an inert atmosphere, to a solution of solketal (3.5 g, 26.7 mmoles) in 50.0 ml of 1,2-dimethoxyethane. After 20 minutes, 5.0 g of 2,7-dibromo-9,9-bis(3′-bromopropyl)fluorene (5.0 g, 8.9 mmoles) dissolved in 15.0 ml of 1,2-dimethoxyethane are added.

Workup

  1. additionare added

Sources & evidence

ORD record
ord-84c3bef1059a4d05a77f3e6de7bec0ad
Source dataset
uspto-grants-2016_03
Patent number
US09290483B2

Reaction notes

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