Pyrrolidine → 1-((Z)-3-tributylstannanylallyl)pyrrolidine

HRID 927908Notes

Reaction equation

HRID 927908 reaction equation
[CH2:1]([N:3]([CH2:20][CH3:21])[CH2:4]/[CH:5]=[CH:6]\[Sn:7]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH2:9][CH2:10][CH3:11])[CH3:2].BrC/C=C\[Sn](CCCC)(CCCC)CCCC.N1CCCC1>>[CH2:8]([Sn:7]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:12][CH2:13][CH2:14][CH3:15])/[CH:6]=[CH:5]\[CH2:4][N:3]1[CH2:1][CH2:2][CH2:21][CH2:20]1)[CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 3

HCID 31268PyrrolidineHCID 10949620[(Z)-3-bromoprop-1-enyl]-tributylstannane2×HCID 86684726N,N-diethyl-N-((Z)-1-tributylstannanylprop-1-en-3-yl)amine

Product 1

HCID 666864121-((Z)-3-tributylstannanylallyl)pyrrolidine

Procedure

Prepared by proceeding in a similar manner to Intermediate 11 starting from ((Z)-3-bromoprop-1-enyl)tributylstannane (Intermediate 12) and pyrrolidine.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-641ac891d7cc4690ab81b726ab9c8593
Source dataset
uspto-grants-2016_03
Patent number
US09290472B2

Reaction notes

Loading…